Characterisation of olivine-type LiMn<inf>x</inf>Fe<inf>1-x</inf>PO<inf>4</inf> cathode materials

Yao, J; Bewlay, S; Konstantionv, K; Drozd, VA; Liu, RS; Wang, XL; Liu, HK; Wang, GX

Characterisation of olivine-type LiMn<inf>x</inf>Fe<inf>1-x</inf>PO<inf>4</inf> cathode materials

Yao, J Bewlay, S Konstantionv, K Drozd, VA Liu, RS Wang, XL Liu, HK Wang, GX

Permalink

Publication Type:: Journal Article
Citation:: Journal of Alloys and Compounds, 2006, 425 (1-2), pp. 362 - 366
Issue Date:: 2006-11-30

Closed Access

	Filename	Description	Size
	2009005979OK.pdf		535.41 kB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Yao, J	en_US
dc.contributor.author	Bewlay, S	en_US
dc.contributor.author	Konstantionv, K	en_US
dc.contributor.author	Drozd, VA	en_US
dc.contributor.author	Liu, RS	en_US
dc.contributor.author	Wang, XL	en_US
dc.contributor.author	Liu, HK	en_US
dc.contributor.author	Wang, GX https://orcid.org/0000-0003-4295-8578	en_US
dc.date.issued	2006-11-30	en_US
dc.identifier.citation	Journal of Alloys and Compounds, 2006, 425 (1-2), pp. 362 - 366	en_US
dc.identifier.issn	0925-8388	en_US
dc.identifier.uri	http://hdl.handle.net/10453/13644
dc.description.abstract	A series of LiMnxFe1-xPO4 (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) compounds were synthesised by a sol-gel preparation route. X-ray diffraction and Rietveld structure refinement revealed that the lattice parameters (a, b and c) of orthorhombic LiMnxFe1-xPO4 increase with increasing Mn content. Magnetic susceptibility measurements show antiferromagnetic behaviour for LiMnxFe1-xPO4 samples. The electrochemical properties of LiMnxFe1-xPO4 as cathodes in lithium-ion cells were tested via cyclic voltammetry and galvanostatic charge/discharge measurements. The electrochemical performance of LiMnxFe1-xPO4 degrades with increasing Mn content. © 2006 Elsevier B.V. All rights reserved.	en_US
dc.relation	http://purl.org/au-research/grants/arc/LP0453766
dc.relation.ispartof	Journal of Alloys and Compounds	en_US
dc.relation.isbasedon	10.1016/j.jallcom.2006.01.038	en_US
dc.subject.classification	Materials	en_US
dc.title	Characterisation of olivine-type LiMn<inf>x</inf>Fe<inf>1-x</inf>PO<inf>4</inf> cathode materials	en_US
dc.type	Journal Article
utslib.citation.volume	1-2	en_US
utslib.citation.volume	425	en_US
utslib.for	0912 Materials Engineering	en_US
utslib.for	0204 Condensed Matter Physics	en_US
utslib.for	0914 Resources Engineering and Extractive Metallurgy	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	1-2	en_US
pubs.publication-status	Published	en_US
pubs.volume	425	en_US

Abstract:

A series of LiMnxFe1-xPO4 (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) compounds were synthesised by a sol-gel preparation route. X-ray diffraction and Rietveld structure refinement revealed that the lattice parameters (a, b and c) of orthorhombic LiMnxFe1-xPO4 increase with increasing Mn content. Magnetic susceptibility measurements show antiferromagnetic behaviour for LiMnxFe1-xPO4 samples. The electrochemical properties of LiMnxFe1-xPO4 as cathodes in lithium-ion cells were tested via cyclic voltammetry and galvanostatic charge/discharge measurements. The electrochemical performance of LiMnxFe1-xPO4 degrades with increasing Mn content. © 2006 Elsevier B.V. All rights reserved.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/13644