Metal-organic-framework-derived formation of Co–N-doped carbon materials for efficient oxygen reduction reaction

Tian, H; Zhang, C; Su, P; Shen, Z; Liu, H; Wang, G; Liu, S; Liu, J

Metal-organic-framework-derived formation of Co–N-doped carbon materials for efficient oxygen reduction reaction

Tian, H

Zhang, C Su, P Shen, Z Liu, H

Wang, G

Liu, S Liu, J

Permalink

Publisher:: ELSEVIER
Publication Type:: Journal Article
Citation:: Journal of Energy Chemistry, 2020, 40, pp. 137-143
Issue Date:: 2020-01-01

Closed Access

	Filename	Description	Size
	1-s2.0-S2095495619301731-main.pdf	Published version	2.06 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Tian, H https://orcid.org/0000-0002-9581-0027
dc.contributor.author	Zhang, C
dc.contributor.author	Su, P
dc.contributor.author	Shen, Z
dc.contributor.author	Liu, H https://orcid.org/0000-0003-0266-9472
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.contributor.author	Liu, S
dc.contributor.author	Liu, J
dc.date.accessioned	2020-12-18T03:22:27Z
dc.date.available	2020-12-18T03:22:27Z
dc.date.issued	2020-01-01
dc.identifier.citation	Journal of Energy Chemistry, 2020, 40, pp. 137-143
dc.identifier.issn	2095-4956
dc.identifier.issn	2095-4956
dc.identifier.uri	http://hdl.handle.net/10453/144841
dc.description.abstract	© 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences Non-precious metal nitrogen-doped carbonaceous materials have attracted tremendous attention in the field of electrochemical energy storage and conversion. Herein, we report the designed synthesis of a novel series of Co-N-C nanocomposites and their evaluation of electrochemical properties. Novel yolk-shell structured Co nanoparticles@polymer materials are fabricated from the facile coating polymer strategy on the surface of ZIF-67. After calcination in nitrogen atmosphere, the Co–N–C nanocomposites in which cobalt metal nanoparticles are embedded in the highly porous and graphitic carbon matrix are successfully achieved. The cobalt nanoparticles containing cobalt metal crystallites with an oxidized shell and/or smaller (or amorphous) cobalt-oxide deposits appear on the surface of graphitic carbons. The prepared Co–N–C nanoparticles showed favorable electrocatalytic activity for oxygen reduction reactions, which is attributed to its high graphitic degree, large surface area and the large amount existence of Co–N active sites.
dc.language	English
dc.publisher	ELSEVIER
dc.relation	http://purl.org/au-research/grants/arc/DP180102297
dc.relation	http://purl.org/au-research/grants/arc/FT180100705
dc.relation.ispartof	Journal of Energy Chemistry
dc.relation.isbasedon	10.1016/j.jechem.2019.03.004
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0305 Organic Chemistry
dc.subject.classification	Physical Chemistry
dc.title	Metal-organic-framework-derived formation of Co–N-doped carbon materials for efficient oxygen reduction reaction
dc.type	Journal Article
utslib.citation.volume	40
utslib.for	0305 Organic Chemistry
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney
utslib.copyright.status	closed_access	*
pubs.consider-herdc	false
dc.date.updated	2020-12-18T03:22:12Z
pubs.publication-status	Published
pubs.volume	40

Abstract:

© 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences Non-precious metal nitrogen-doped carbonaceous materials have attracted tremendous attention in the field of electrochemical energy storage and conversion. Herein, we report the designed synthesis of a novel series of Co-N-C nanocomposites and their evaluation of electrochemical properties. Novel yolk-shell structured Co nanoparticles@polymer materials are fabricated from the facile coating polymer strategy on the surface of ZIF-67. After calcination in nitrogen atmosphere, the Co–N–C nanocomposites in which cobalt metal nanoparticles are embedded in the highly porous and graphitic carbon matrix are successfully achieved. The cobalt nanoparticles containing cobalt metal crystallites with an oxidized shell and/or smaller (or amorphous) cobalt-oxide deposits appear on the surface of graphitic carbons. The prepared Co–N–C nanoparticles showed favorable electrocatalytic activity for oxygen reduction reactions, which is attributed to its high graphitic degree, large surface area and the large amount existence of Co–N active sites.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/144841