Reaction Mechanisms of Layered Lithium-Rich Cathode Materials for High-Energy Lithium-Ion Batteries.

Zhao, S; Yan, K; Zhang, J; Sun, B; Wang, G

Reaction Mechanisms of Layered Lithium-Rich Cathode Materials for High-Energy Lithium-Ion Batteries.

Zhao, S Yan, K

Zhang, J

Sun, B

Wang, G

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Publisher:: WILEY-V C H VERLAG GMBH
Publication Type:: Journal Article
Citation:: Angewandte Chemie (International ed. in English), 2021
Issue Date:: 2021-01-01

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Field	Value	Language
dc.contributor.author	Zhao, S
dc.contributor.author	Yan, K https://orcid.org/0000-0002-3623-658X
dc.contributor.author	Zhang, J https://orcid.org/0000-0001-5476-0134
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.date.accessioned	2021-01-13T05:52:50Z
dc.date.available	2021-01-13T05:52:50Z
dc.date.issued	2021-01-01
dc.identifier.citation	Angewandte Chemie (International ed. in English), 2021
dc.identifier.issn	1433-7851
dc.identifier.issn	1521-3773
dc.identifier.uri	http://hdl.handle.net/10453/145395
dc.description.abstract	Layered lithium-rich cathode materials have attracted extensive interest owing to their high theoretical specific capacity (320-350 mA h g-1 ). However, poor cycling stability and sluggish reaction kinetics inhibit their practical applications. After many years of quiescence, interest in layered lithium-rich cathode materials is expected to revive in answer to our increasing dependence on high-energy-density lithium-ion batteries. Herein, we review recent research progress and in-depth descriptions of the structure characterization and reaction mechanisms of layered lithium-rich manganese-based cathode materials. In particular, we comprehensively summarize the proposed reaction mechanisms of both the cationic redox reaction of transition-metal ions and the anionic redox reaction of oxygen species. Finally, we discuss opportunities and challenges facing the future development of lithium-rich cathode materials for next-generation lithium-ion batteries.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	WILEY-V C H VERLAG GMBH
dc.relation	http://purl.org/au-research/grants/arc/DP170100436
dc.relation	http://purl.org/au-research/grants/arc/DP180102297
dc.relation	http://purl.org/au-research/grants/arc/DE180100036
dc.relation	http://purl.org/au-research/grants/arc/DP200101249
dc.relation.ispartof	Angewandte Chemie (International ed. in English)
dc.relation.isbasedon	10.1002/anie.202000262
dc.rights	info:eu-repo/semantics/restrictedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	Organic Chemistry
dc.title	Reaction Mechanisms of Layered Lithium-Rich Cathode Materials for High-Energy Lithium-Ion Batteries.
dc.type	Journal Article
utslib.location.activity	Germany
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
pubs.consider-herdc	false
dc.date.updated	2021-01-13T05:52:39Z
pubs.publication-status	Published

Abstract:

Layered lithium-rich cathode materials have attracted extensive interest owing to their high theoretical specific capacity (320-350 mA h g-1 ). However, poor cycling stability and sluggish reaction kinetics inhibit their practical applications. After many years of quiescence, interest in layered lithium-rich cathode materials is expected to revive in answer to our increasing dependence on high-energy-density lithium-ion batteries. Herein, we review recent research progress and in-depth descriptions of the structure characterization and reaction mechanisms of layered lithium-rich manganese-based cathode materials. In particular, we comprehensively summarize the proposed reaction mechanisms of both the cationic redox reaction of transition-metal ions and the anionic redox reaction of oxygen species. Finally, we discuss opportunities and challenges facing the future development of lithium-rich cathode materials for next-generation lithium-ion batteries.

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http://hdl.handle.net/10453/145395