Self-assembling RuO2 nanogranulates with few carbon layers as an interconnected nanoporous structure for lithium-oxygen batteries.

Lai, W-H; Zheng, Z; Wang, W; Wang, L; Lei, Y-J; Wang, Y-X; Wang, J-Z; Liu, H-K; Chou, S-L; Dou, S-X

Self-assembling RuO2 nanogranulates with few carbon layers as an interconnected nanoporous structure for lithium-oxygen batteries.

Lai, W-H Zheng, Z Wang, W Wang, L Lei, Y-J Wang, Y-X Wang, J-Z Liu, H-K Chou, S-L Dou, S-X

Permalink

Publisher:: ROYAL SOC CHEMISTRY
Publication Type:: Journal Article
Citation:: Chemical communications (Cambridge, England), 2020, 56, (53), pp. 7253-7256
Issue Date:: 2020-07

Closed Access

	Filename	Description	Size
	d0cc01125h.pdf	Accepted version	2.56 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Lai, W-H
dc.contributor.author	Zheng, Z
dc.contributor.author	Wang, W
dc.contributor.author	Wang, L
dc.contributor.author	Lei, Y-J
dc.contributor.author	Wang, Y-X
dc.contributor.author	Wang, J-Z
dc.contributor.author	Liu, H-K
dc.contributor.author	Chou, S-L
dc.contributor.author	Dou, S-X
dc.date.accessioned	2021-03-07T23:16:09Z
dc.date.available	2021-03-07T23:16:09Z
dc.date.issued	2020-07
dc.identifier.citation	Chemical communications (Cambridge, England), 2020, 56, (53), pp. 7253-7256
dc.identifier.issn	1359-7345
dc.identifier.issn	1364-548X
dc.identifier.uri	http://hdl.handle.net/10453/146879
dc.description.abstract	Electrocatalysis for cathodic oxygen is of great significance for achieving high-performance lithium-oxygen batteries. Herein, we report a facile and green method to prepare an interconnected nanoporous three-dimensional (3D) architecture, which is composed of RuO2 nanogranulates coated with few layers of carbon. The as-prepared 3D nanoporous RuO2@C nanostructure can demonstrate a high initial specific discharge capacity of 4000 mA h g-1 with high round-trip efficiency of 95%. Meanwhile, the nanoporous RuO2@C could achieve stable cycling performance with a fixed capacity of 1500 mA h g-1 over 100 cycles. The terminal discharge and charge potentials of nanoporous RuO2@C are well maintained with minor potential variation of 0.14 and 0.13 V at the 100th cycle, respectively. In addition, the formation of discharge products is monitored by using in situ high-energy synchrotron X-ray diffraction (XRD).
dc.format	Print
dc.language	eng
dc.publisher	ROYAL SOC CHEMISTRY
dc.relation.ispartof	Chemical communications (Cambridge, England)
dc.relation.isbasedon	10.1039/d0cc01125h
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	Organic Chemistry
dc.title	Self-assembling RuO2 nanogranulates with few carbon layers as an interconnected nanoporous structure for lithium-oxygen batteries.
dc.type	Journal Article
utslib.citation.volume	56
utslib.location.activity	England
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney
utslib.copyright.status	closed_access	*
dc.date.updated	2021-03-07T23:16:07Z
pubs.issue	53
pubs.publication-status	Published
pubs.volume	56
utslib.citation.issue	53

Abstract:

Electrocatalysis for cathodic oxygen is of great significance for achieving high-performance lithium-oxygen batteries. Herein, we report a facile and green method to prepare an interconnected nanoporous three-dimensional (3D) architecture, which is composed of RuO2 nanogranulates coated with few layers of carbon. The as-prepared 3D nanoporous RuO2@C nanostructure can demonstrate a high initial specific discharge capacity of 4000 mA h g-1 with high round-trip efficiency of 95%. Meanwhile, the nanoporous RuO2@C could achieve stable cycling performance with a fixed capacity of 1500 mA h g-1 over 100 cycles. The terminal discharge and charge potentials of nanoporous RuO2@C are well maintained with minor potential variation of 0.14 and 0.13 V at the 100th cycle, respectively. In addition, the formation of discharge products is monitored by using in situ high-energy synchrotron X-ray diffraction (XRD).

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/146879