Bimetallic Sulfide/Sulfur Doped T<inf>3</inf>C<inf>2</inf>T<inf>x</inf> MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries

Zang, R; Li, P; Wang, G

Bimetallic Sulfide/Sulfur Doped T<inf>3</inf>C<inf>2</inf>T<inf>x</inf> MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries

Zang, R Li, P Wang, G

Permalink

Publisher:: HIGHER EDUCATION PRESS
Publication Type:: Journal Article
Citation:: Chemical Research in Chinese Universities, 2020, 36, (3), pp. 431-438
Issue Date:: 2020-06-01

Closed Access

	Filename	Description	Size
	Zang2020_Article_BimetallicSulfideSulfurDopedT3.pdf	Published version	1.2 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Zang, R
dc.contributor.author	Li, P
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.date.accessioned	2021-03-14T21:57:39Z
dc.date.available	2021-03-14T21:57:39Z
dc.date.issued	2020-06-01
dc.identifier.citation	Chemical Research in Chinese Universities, 2020, 36, (3), pp. 431-438
dc.identifier.issn	1005-9040
dc.identifier.issn	2210-3171
dc.identifier.uri	http://hdl.handle.net/10453/147114
dc.description.abstract	© 2020, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH. The application of transition metal dichalcogenides(TMDs) as anode materials in sodium-ion batteries (SIBs) has been hindered by low conductivity and poor cyclability. Herein, we report the synthesis of CoxFe1−xS2 bimetallic sulfide/sulfur-doped Ti3C2 MXene nanocomposites(CoxFe1−xS2@S-Ti3C2) by a facile co-precipitation process and thermal-sulfurization reaction. The interconnected 3D frameworks consisting of MXene nanosheets can effectively buffer the volume change and enhance the charge transfer. In particular, sulfur-doped MXene nanosheets provide rich active sites for sodium storage and restrain sulfur loss during charging/discharging processes, leading the increase of specific capacity and cycling the stability of anode materials. As a result, CoxFe1−xS2@S-Ti3C2 anodes exhibited high capacity, high rate capability and long cycle life(399 m·Ah/g at 5 A/g with an 94% capacity retention after 600 cycles).
dc.language	English
dc.publisher	HIGHER EDUCATION PRESS
dc.relation.ispartof	Chemical Research in Chinese Universities
dc.relation.isbasedon	10.1007/s40242-020-0120-4
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.title	Bimetallic Sulfide/Sulfur Doped T<inf>3</inf>C<inf>2</inf>T<inf>x</inf> MXene Nanocomposites as High-performance Anode Materials for Sodium-ion Batteries
dc.type	Journal Article
utslib.citation.volume	36
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
dc.date.updated	2021-03-14T21:57:37Z
pubs.issue	3
pubs.publication-status	Published
pubs.volume	36
utslib.citation.issue	3

Abstract:

© 2020, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH. The application of transition metal dichalcogenides(TMDs) as anode materials in sodium-ion batteries (SIBs) has been hindered by low conductivity and poor cyclability. Herein, we report the synthesis of CoxFe1−xS2 bimetallic sulfide/sulfur-doped Ti3C2 MXene nanocomposites(CoxFe1−xS2@S-Ti3C2) by a facile co-precipitation process and thermal-sulfurization reaction. The interconnected 3D frameworks consisting of MXene nanosheets can effectively buffer the volume change and enhance the charge transfer. In particular, sulfur-doped MXene nanosheets provide rich active sites for sodium storage and restrain sulfur loss during charging/discharging processes, leading the increase of specific capacity and cycling the stability of anode materials. As a result, CoxFe1−xS2@S-Ti3C2 anodes exhibited high capacity, high rate capability and long cycle life(399 m·Ah/g at 5 A/g with an 94% capacity retention after 600 cycles).

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/147114