Metal-organic frameworks as separators and electrolytes for lithium-sulfur batteries

Chu, Z; Gao, X; Wang, C; Wang, T; Wang, G

Metal-organic frameworks as separators and electrolytes for lithium-sulfur batteries

Chu, Z Gao, X Wang, C Wang, T Wang, G

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Publisher:: Royal Society of Chemistry
Publication Type:: Journal Article
Citation:: Journal of Materials Chemistry A, 2021, 9, (12), pp. 7301-7316
Issue Date:: 2021-03-28

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Field	Value	Language
dc.contributor.author	Chu, Z
dc.contributor.author	Gao, X
dc.contributor.author	Wang, C
dc.contributor.author	Wang, T
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.date.accessioned	2022-02-08T05:14:17Z
dc.date.available	2022-02-08T05:14:17Z
dc.date.issued	2021-03-28
dc.identifier.citation	Journal of Materials Chemistry A, 2021, 9, (12), pp. 7301-7316
dc.identifier.issn	2050-7488
dc.identifier.issn	2050-7496
dc.identifier.uri	http://hdl.handle.net/10453/154287
dc.description.abstract	Due to high energy density and low cost, lithium-sulfur batteries (LSBs) have been regarded as the next generation of energy storage systems. As indispensable parts of LSBs, separators and solid electrolytes play an important role in inhibiting dendrite growth and eliminating short-circuit risks. Their development can fundamentally improve the performance of LSBs. In recent years, metal-organic frameworks (MOFs), as porous crystalline inorganic-organic materials with high porosity, uniform pore size distribution, customizable structure, and easy functionalization, are used as molecular sieves to uniformly deposit lithium ions and combine high-soluble solid solution polysulfides (PSs), which have become an emerging research direction. In this review, we are devoted to summarizing the design strategy of MOF-based separators and electrolytes based on MOFs and MOF-derived materials for LSBs. By discussing the pioneer works, both opportunities and challenges in each category are presented. Additionally, some design principles for MOF-based separators and MOF-based electrolytes, as well as the future directions for further development are provided.
dc.language	English
dc.publisher	Royal Society of Chemistry
dc.relation.ispartof	Journal of Materials Chemistry A
dc.relation.isbasedon	10.1039/d0ta11624f
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 0912 Materials Engineering, 0915 Interdisciplinary Engineering
dc.title	Metal-organic frameworks as separators and electrolytes for lithium-sulfur batteries
dc.type	Journal Article
utslib.citation.volume	9
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	0912 Materials Engineering
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
pubs.consider-herdc	false
dc.date.updated	2022-02-08T05:14:15Z
pubs.issue	12
pubs.publication-status	Published
pubs.volume	9
utslib.citation.issue	12

Abstract:

Due to high energy density and low cost, lithium-sulfur batteries (LSBs) have been regarded as the next generation of energy storage systems. As indispensable parts of LSBs, separators and solid electrolytes play an important role in inhibiting dendrite growth and eliminating short-circuit risks. Their development can fundamentally improve the performance of LSBs. In recent years, metal-organic frameworks (MOFs), as porous crystalline inorganic-organic materials with high porosity, uniform pore size distribution, customizable structure, and easy functionalization, are used as molecular sieves to uniformly deposit lithium ions and combine high-soluble solid solution polysulfides (PSs), which have become an emerging research direction. In this review, we are devoted to summarizing the design strategy of MOF-based separators and electrolytes based on MOFs and MOF-derived materials for LSBs. By discussing the pioneer works, both opportunities and challenges in each category are presented. Additionally, some design principles for MOF-based separators and MOF-based electrolytes, as well as the future directions for further development are provided.

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http://hdl.handle.net/10453/154287