Naphthalene diimide-based electron transport materials for perovskite solar cells

Jameel, MA; Yang, TC-J; Wilson, GJ; Evans, RA; Gupta, A; Langford, SJ

Naphthalene diimide-based electron transport materials for perovskite solar cells

Jameel, MA Yang, TC-J Wilson, GJ Evans, RA Gupta, A Langford, SJ

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Publisher:: Royal Society of Chemistry
Publication Type:: Journal Article
Citation:: Journal of Materials Chemistry A, 2021, 9, (48), pp. 27170-27192
Issue Date:: 2021-11-08

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Field	Value	Language
dc.contributor.author	Jameel, MA
dc.contributor.author	Yang, TC-J
dc.contributor.author	Wilson, GJ
dc.contributor.author	Evans, RA
dc.contributor.author	Gupta, A
dc.contributor.author	Langford, SJ
dc.date.accessioned	2022-02-11T06:40:44Z
dc.date.available	2022-02-11T06:40:44Z
dc.date.issued	2021-11-08
dc.identifier.citation	Journal of Materials Chemistry A, 2021, 9, (48), pp. 27170-27192
dc.identifier.issn	2050-7488
dc.identifier.issn	2050-7496
dc.identifier.uri	http://hdl.handle.net/10453/154412
dc.description.abstract	The development of perovskite solar cells (PSCs) as an efficient and cost-effective alternative to traditional approaches to solar energy transduction has received much recent attention, and there has been considerable progress made with reported power conversion efficiencies now surpassing 25%. This development is encouraging and is a result of intensive research on device design, factors affecting long-term stability of PSCs, and systematic material development in which electron transport layer (ETL) materials play a crucial role to afford high-performance PSC devices. ETL materials, including (6-(1,10-phenanthrolin-3-yl)naphthalen-2-yl)diphenylphosphine oxide (Phen-NaDPO), and n-type materials based on the naphthalene diimide (NDI) structure, appear to be amongst the most promising materials to date. This article provides an up-to-date review on organic n-type ETL materials, both polymeric and small molecules, based on NDI format, detailing reports of structures with key relevant parameters, such as the efficiency and stability of PSCs. The review is written from a perspective of organic chemistry and we believe this will provide fundamental advice on the future design of new ETL materials based on NDIs that will afford more efficient and stable PSCs.
dc.language	English
dc.publisher	Royal Society of Chemistry
dc.relation.ispartof	Journal of Materials Chemistry A
dc.relation.isbasedon	10.1039/d1ta08424k
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 0912 Materials Engineering, 0915 Interdisciplinary Engineering
dc.title	Naphthalene diimide-based electron transport materials for perovskite solar cells
dc.type	Journal Article
utslib.citation.volume	9
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	0912 Materials Engineering
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	open_access	*
pubs.consider-herdc	false
dc.date.updated	2022-02-11T06:40:41Z
pubs.issue	48
pubs.publication-status	Published
pubs.volume	9
utslib.citation.issue	48

Abstract:

The development of perovskite solar cells (PSCs) as an efficient and cost-effective alternative to traditional approaches to solar energy transduction has received much recent attention, and there has been considerable progress made with reported power conversion efficiencies now surpassing 25%. This development is encouraging and is a result of intensive research on device design, factors affecting long-term stability of PSCs, and systematic material development in which electron transport layer (ETL) materials play a crucial role to afford high-performance PSC devices. ETL materials, including (6-(1,10-phenanthrolin-3-yl)naphthalen-2-yl)diphenylphosphine oxide (Phen-NaDPO), and n-type materials based on the naphthalene diimide (NDI) structure, appear to be amongst the most promising materials to date. This article provides an up-to-date review on organic n-type ETL materials, both polymeric and small molecules, based on NDI format, detailing reports of structures with key relevant parameters, such as the efficiency and stability of PSCs. The review is written from a perspective of organic chemistry and we believe this will provide fundamental advice on the future design of new ETL materials based on NDIs that will afford more efficient and stable PSCs.

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http://hdl.handle.net/10453/154412