Porous Ti3C2Tx MXene for Ultrahigh-Rate Sodium-Ion Storage with Long Cycle Life

Xie, X; Kretschmer, K; Anasori, B; Sun, B; Wang, G; Gogotsi, Y

Porous Ti3C2Tx MXene for Ultrahigh-Rate Sodium-Ion Storage with Long Cycle Life

Xie, X Kretschmer, K Anasori, B Sun, B

Wang, G

Gogotsi, Y

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Publisher:: AMER CHEMICAL SOC
Publication Type:: Journal Article
Citation:: ACS Applied Nano Materials, 2018, 1, (2), pp. 505-511
Issue Date:: 2018-02-23

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Field	Value	Language
dc.contributor.author	Xie, X
dc.contributor.author	Kretschmer, K
dc.contributor.author	Anasori, B
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.contributor.author	Gogotsi, Y
dc.date.accessioned	2022-08-24T03:31:39Z
dc.date.available	2022-08-24T03:31:39Z
dc.date.issued	2018-02-23
dc.identifier.citation	ACS Applied Nano Materials, 2018, 1, (2), pp. 505-511
dc.identifier.issn	2574-0970
dc.identifier.issn	2574-0970
dc.identifier.uri	http://hdl.handle.net/10453/160766
dc.description.abstract	The development of anode materials remains a challenge to satisfy the requirements of sodium-ion storage for large-scale energy-storage applications, which is ascribed to the low kinetics of ionic/electron transfer of electrode materials. Here we show that the controlled anisotropic assembly of highly conductive Ti3C2Tx MXene nanosheets to form a porous structure can enhance the sodium-ion storage kinetics. At high current densities of 1 and 10 A g-1, the porous Ti3C2Tx electrode delivered capacities of 166 and 124 mA h g-1, respectively. Even at an extremely high current density of 100 A g-1, a capacity of 24 mA h g-1 could be achieved. The porous Ti3C2Tx electrode also exhibited a long cycle life that can be extended to 1000 cycles with no capacity decay at a current density of 1 A g-1. This work demonstrates successful control of the Ti3C2Tx architecture to push electrochemical sodium-ion storage closer to large-scale applications and is expected to shed light on the rational utilization of the outstanding properties of MXenes by controlling their microscopic assembly.
dc.language	English
dc.publisher	AMER CHEMICAL SOC
dc.relation.ispartof	ACS Applied Nano Materials
dc.relation.isbasedon	10.1021/acsanm.8b00045
dc.rights	info:eu-repo/semantics/closedAccess
dc.title	Porous Ti3C2Tx MXene for Ultrahigh-Rate Sodium-Ion Storage with Long Cycle Life
dc.type	Journal Article
utslib.citation.volume	1
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
dc.date.updated	2022-08-24T03:31:37Z
pubs.issue	2
pubs.publication-status	Published
pubs.volume	1
utslib.citation.issue	2

Abstract:

The development of anode materials remains a challenge to satisfy the requirements of sodium-ion storage for large-scale energy-storage applications, which is ascribed to the low kinetics of ionic/electron transfer of electrode materials. Here we show that the controlled anisotropic assembly of highly conductive Ti3C2Tx MXene nanosheets to form a porous structure can enhance the sodium-ion storage kinetics. At high current densities of 1 and 10 A g-1, the porous Ti3C2Tx electrode delivered capacities of 166 and 124 mA h g-1, respectively. Even at an extremely high current density of 100 A g-1, a capacity of 24 mA h g-1 could be achieved. The porous Ti3C2Tx electrode also exhibited a long cycle life that can be extended to 1000 cycles with no capacity decay at a current density of 1 A g-1. This work demonstrates successful control of the Ti3C2Tx architecture to push electrochemical sodium-ion storage closer to large-scale applications and is expected to shed light on the rational utilization of the outstanding properties of MXenes by controlling their microscopic assembly.

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http://hdl.handle.net/10453/160766