Systematically Studying the Effect of Fluoride on the Properties of Cyclophanes Bearing Naphthalene Diimide and Dialkoxyaryl Groups.

Young, NA; Drew, SC; Maniam, S; Langford, SJ

Systematically Studying the Effect of Fluoride on the Properties of Cyclophanes Bearing Naphthalene Diimide and Dialkoxyaryl Groups.

Young, NA Drew, SC Maniam, S Langford, SJ

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Publisher:: WILEY-V C H VERLAG GMBH
Publication Type:: Journal Article
Citation:: Chem Asian J, 2017, 12, (13), pp. 1668-1675
Issue Date:: 2017-07-04

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Field	Value	Language
dc.contributor.author	Young, NA
dc.contributor.author	Drew, SC
dc.contributor.author	Maniam, S
dc.contributor.author	Langford, SJ
dc.date.accessioned	2022-10-28T06:54:18Z
dc.date.available	2022-10-28T06:54:18Z
dc.date.issued	2017-07-04
dc.identifier.citation	Chem Asian J, 2017, 12, (13), pp. 1668-1675
dc.identifier.issn	1861-4728
dc.identifier.issn	1861-471X
dc.identifier.uri	http://hdl.handle.net/10453/162830
dc.description.abstract	Anion-π interactions between the Lewis basic anion fluoride and π-acidic naphthalene diimide was systematically studied in a series of cyclophanes in which the properties are modulated through the influence of a second, electron-rich aromatic unit. The systems and subsequently generated radical anions, upon addition of fluoride, were studied by absorption spectroscopic and EPR techniques. The results infer a modulation as a result of the nature and strength of the π-π interaction in the macrocyclic structure.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	WILEY-V C H VERLAG GMBH
dc.relation	http://purl.org/au-research/grants/arc/DP170104477
dc.relation	http://purl.org/au-research/grants/arc/DP130101861
dc.relation.ispartof	Chem Asian J
dc.relation.isbasedon	10.1002/asia.201700459
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.title	Systematically Studying the Effect of Fluoride on the Properties of Cyclophanes Bearing Naphthalene Diimide and Dialkoxyaryl Groups.
dc.type	Journal Article
utslib.citation.volume	12
utslib.location.activity	Germany
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
dc.date.updated	2022-10-28T06:54:17Z
pubs.issue	13
pubs.publication-status	Published
pubs.volume	12
utslib.citation.issue	13

Abstract:

Anion-π interactions between the Lewis basic anion fluoride and π-acidic naphthalene diimide was systematically studied in a series of cyclophanes in which the properties are modulated through the influence of a second, electron-rich aromatic unit. The systems and subsequently generated radical anions, upon addition of fluoride, were studied by absorption spectroscopic and EPR techniques. The results infer a modulation as a result of the nature and strength of the π-π interaction in the macrocyclic structure.

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http://hdl.handle.net/10453/162830