Lanthanum-1,2,3-Triazole-Based 2D Coordination Polymer is an Efficient Catalyst for the Oxidation of Olefins.

Belay, Y; Muller, A; Williams, DBG

Lanthanum-1,2,3-Triazole-Based 2D Coordination Polymer is an Efficient Catalyst for the Oxidation of Olefins.

Belay, Y Muller, A Williams, DBG

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Publisher:: AMER CHEMICAL SOC
Publication Type:: Journal Article
Citation:: Inorg Chem, 2022, 61, (21), pp. 8226-8232
Issue Date:: 2022-05-30

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Field	Value	Language
dc.contributor.author	Belay, Y
dc.contributor.author	Muller, A
dc.contributor.author	Williams, DBG
dc.date.accessioned	2023-02-16T05:04:53Z
dc.date.available	2023-02-16T05:04:53Z
dc.date.issued	2022-05-30
dc.identifier.citation	Inorg Chem, 2022, 61, (21), pp. 8226-8232
dc.identifier.issn	0020-1669
dc.identifier.issn	1520-510X
dc.identifier.uri	http://hdl.handle.net/10453/166206
dc.description.abstract	A new two-dimensional (2D) coordination polymer (CP) [La(C18H14N3O6)2(H2O)(OH)]n has been prepared from a 1,2,3-triazole linker and lanthanum nitrate hexahydrate in DMF. The La-CP was characterized by single-crystal X-ray crystallography, highlighting the binding motif at La ions and the fact that the material contains channels with entrapped solvent. The CP showed good catalytic activity for the oxidation of a wide variety of olefins (linear, cyclic, aromatic, and functionalized alkenes) to aldehydes. Mechanistic studies show that the oxidation reaction proceeds via a non-free-radical mechanism. The catalyst could be recovered and reused five times without major changes in activity for the oxidation of styrene to benzaldehyde.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	AMER CHEMICAL SOC
dc.relation.ispartof	Inorg Chem
dc.relation.isbasedon	10.1021/acs.inorgchem.2c00648
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0302 Inorganic Chemistry, 0306 Physical Chemistry (incl. Structural), 0399 Other Chemical Sciences
dc.subject.classification	Inorganic & Nuclear Chemistry
dc.title	Lanthanum-1,2,3-Triazole-Based 2D Coordination Polymer is an Efficient Catalyst for the Oxidation of Olefins.
dc.type	Journal Article
utslib.citation.volume	61
utslib.location.activity	United States
utslib.for	0302 Inorganic Chemistry
utslib.for	0306 Physical Chemistry (incl. Structural)
utslib.for	0399 Other Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	closed_access	*
dc.date.updated	2023-02-16T05:04:52Z
pubs.issue	21
pubs.publication-status	Published
pubs.volume	61
utslib.citation.issue	21

Abstract:

A new two-dimensional (2D) coordination polymer (CP) [La(C18H14N3O6)2(H2O)(OH)]n has been prepared from a 1,2,3-triazole linker and lanthanum nitrate hexahydrate in DMF. The La-CP was characterized by single-crystal X-ray crystallography, highlighting the binding motif at La ions and the fact that the material contains channels with entrapped solvent. The CP showed good catalytic activity for the oxidation of a wide variety of olefins (linear, cyclic, aromatic, and functionalized alkenes) to aldehydes. Mechanistic studies show that the oxidation reaction proceeds via a non-free-radical mechanism. The catalyst could be recovered and reused five times without major changes in activity for the oxidation of styrene to benzaldehyde.

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http://hdl.handle.net/10453/166206