Advanced nanoengineering strategies endow high-performance layered transition-metal oxide cathodes for sodium-ion batteries

Xiao, J; Xiao, Y; Li, J; Gong, C; Nie, X; Gao, H; Sun, B; Liu, H; Wang, G

Advanced nanoengineering strategies endow high-performance layered transition-metal oxide cathodes for sodium-ion batteries

Xiao, J Xiao, Y Li, J Gong, C Nie, X Gao, H

Sun, B

Liu, H

Wang, G

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Publisher:: WILEY
Publication Type:: Journal Article
Citation:: SmartMat, 2023, 4, (5)
Issue Date:: 2023-10-01

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Field	Value	Language
dc.contributor.author	Xiao, J
dc.contributor.author	Xiao, Y
dc.contributor.author	Li, J
dc.contributor.author	Gong, C
dc.contributor.author	Nie, X
dc.contributor.author	Gao, H https://orcid.org/0000-0002-4431-631X
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Liu, H https://orcid.org/0000-0003-0266-9472
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.date.accessioned	2024-02-21T01:15:55Z
dc.date.available	2024-02-21T01:15:55Z
dc.date.issued	2023-10-01
dc.identifier.citation	SmartMat, 2023, 4, (5)
dc.identifier.issn	2766-8525
dc.identifier.issn	2688-819X
dc.identifier.uri	http://hdl.handle.net/10453/175785
dc.description.abstract	Considering the abundance and low price of sodium, sodium-ion batteries (SIBs) have shown great potential as an alternative to existing lithium-based batteries in large-scale energy storage systems, including electric automobiles and smart grids. Cathode materials, which largely decide the cost and the electrochemical performance of the full SIBs, have been extensively studied. Among the reported cathodes, layered transition-metal oxides (LTMOs) are regarded as the most extremely promising candidates for the commercial application of the SIBs owing to their high specific capacity, superior redox potential, and suitable scalable preparation. Nevertheless, irreversible structural evolution, sluggish kinetics, and water sensitivity are still the critical bottlenecks for their practical utilization. Nanoengineering may offer an opportunity to address the above issues by increasing reactivity, shortening diffusion pathways, and strengthening structural stability. Herein, a comprehensive summary of the modification strategies for LTMOs is presented, emphasizing optimizing the structure, restraining detrimental phase transition, and promoting diffusion kinetics. This review intends to facilitate an in-depth understanding of structure–composition–property correlation and offer guidance to the further development of the LTMO cathodes for next-generation energy storage systems.
dc.language	English
dc.publisher	WILEY
dc.relation	http://purl.org/au-research/grants/arc/DP180102297
dc.relation	http://purl.org/au-research/grants/arc/FT180100705
dc.relation.ispartof	SmartMat
dc.relation.isbasedon	10.1002/smm2.1211
dc.rights	info:eu-repo/semantics/openAccess
dc.title	Advanced nanoengineering strategies endow high-performance layered transition-metal oxide cathodes for sodium-ion batteries
dc.type	Journal Article
utslib.citation.volume	4
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access	*
dc.date.updated	2024-02-21T01:15:52Z
pubs.issue	5
pubs.publication-status	Published
pubs.volume	4
utslib.citation.issue	5

Abstract:

Considering the abundance and low price of sodium, sodium-ion batteries (SIBs) have shown great potential as an alternative to existing lithium-based batteries in large-scale energy storage systems, including electric automobiles and smart grids. Cathode materials, which largely decide the cost and the electrochemical performance of the full SIBs, have been extensively studied. Among the reported cathodes, layered transition-metal oxides (LTMOs) are regarded as the most extremely promising candidates for the commercial application of the SIBs owing to their high specific capacity, superior redox potential, and suitable scalable preparation. Nevertheless, irreversible structural evolution, sluggish kinetics, and water sensitivity are still the critical bottlenecks for their practical utilization. Nanoengineering may offer an opportunity to address the above issues by increasing reactivity, shortening diffusion pathways, and strengthening structural stability. Herein, a comprehensive summary of the modification strategies for LTMOs is presented, emphasizing optimizing the structure, restraining detrimental phase transition, and promoting diffusion kinetics. This review intends to facilitate an in-depth understanding of structure–composition–property correlation and offer guidance to the further development of the LTMO cathodes for next-generation energy storage systems.

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http://hdl.handle.net/10453/175785