Strategies to improve metal-organic frameworks and their derived oxides as lithium storage anode materials

Li, Q; Han, N; Chai, J; Zhang, W; Du, J; Tian, H; Liu, H; Wang, G; Tang, B

Strategies to improve metal-organic frameworks and their derived oxides as lithium storage anode materials

Li, Q Han, N Chai, J Zhang, W Du, J Tian, H

Liu, H Wang, G

Tang, B

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Publisher:: PERGAMON-ELSEVIER SCIENCE LTD
Publication Type:: Journal Article
Citation:: Energy, 2023, 282
Issue Date:: 2023-11-01

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Field	Value	Language
dc.contributor.author	Li, Q
dc.contributor.author	Han, N
dc.contributor.author	Chai, J
dc.contributor.author	Zhang, W
dc.contributor.author	Du, J
dc.contributor.author	Tian, H https://orcid.org/0000-0002-9581-0027
dc.contributor.author	Liu, H
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.contributor.author	Tang, B
dc.date.accessioned	2024-03-13T03:11:28Z
dc.date.available	2024-03-13T03:11:28Z
dc.date.issued	2023-11-01
dc.identifier.citation	Energy, 2023, 282
dc.identifier.issn	0360-5442
dc.identifier.issn	1873-6785
dc.identifier.uri	http://hdl.handle.net/10453/176618
dc.description.abstract	Lithium-ion batteries (LIBs) are widely used as energy storage technology in emerging markets such as electric vehicles. The development of anode materials that can replace graphite materials is a hotspot of current research. Metal-organic frameworks (MOFs), as a kind of important porous inorganic organic hybrid crystals, have been developed and used as anode materials for LIBs. MOFs can be used as precursors for transition metal oxides (TMOs) with nanostructures based on unique properties such as their unique structure and morphological characteristic, and controllable skeleton composition. In this review, the application and recent progress of MOFs and their derived TMOs in anode materials for LIBs are reviewed. Attention is also paid to their electrochemical mechanisms and the mechanism of the cyclic capacity enhancement phenomenon. Finally, the challenges of MOFs and their derived TMOs as LIBs anode materials are discussed, and modification strategies to improve their electrochemical performance are analyzed and summarized.
dc.language	English
dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD
dc.relation	http://purl.org/au-research/grants/arc/FT180100705
dc.relation.ispartof	Energy
dc.relation.isbasedon	10.1016/j.energy.2023.128378
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0913 Mechanical Engineering, 0914 Resources Engineering and Extractive Metallurgy, 0915 Interdisciplinary Engineering
dc.subject.classification	Energy
dc.subject.classification	4008 Electrical engineering
dc.subject.classification	4012 Fluid mechanics and thermal engineering
dc.subject.classification	4017 Mechanical engineering
dc.title	Strategies to improve metal-organic frameworks and their derived oxides as lithium storage anode materials
dc.type	Journal Article
utslib.citation.volume	282
utslib.for	0913 Mechanical Engineering
utslib.for	0914 Resources Engineering and Extractive Metallurgy
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access	*
dc.date.updated	2024-03-13T03:11:22Z
pubs.publication-status	Published
pubs.volume	282

Abstract:

Lithium-ion batteries (LIBs) are widely used as energy storage technology in emerging markets such as electric vehicles. The development of anode materials that can replace graphite materials is a hotspot of current research. Metal-organic frameworks (MOFs), as a kind of important porous inorganic organic hybrid crystals, have been developed and used as anode materials for LIBs. MOFs can be used as precursors for transition metal oxides (TMOs) with nanostructures based on unique properties such as their unique structure and morphological characteristic, and controllable skeleton composition. In this review, the application and recent progress of MOFs and their derived TMOs in anode materials for LIBs are reviewed. Attention is also paid to their electrochemical mechanisms and the mechanism of the cyclic capacity enhancement phenomenon. Finally, the challenges of MOFs and their derived TMOs as LIBs anode materials are discussed, and modification strategies to improve their electrochemical performance are analyzed and summarized.

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http://hdl.handle.net/10453/176618