Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review

Shipitsyn, V; Jayakumar, R; Zuo, W; Sun, B; Ma, L

Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review

Shipitsyn, V Jayakumar, R Zuo, W Sun, B

Ma, L

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Publisher:: MDPI
Publication Type:: Journal Article
Citation:: Batteries, 2023, 9, (9)
Issue Date:: 2023-09-01

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Field	Value	Language
dc.contributor.author	Shipitsyn, V
dc.contributor.author	Jayakumar, R
dc.contributor.author	Zuo, W
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Ma, L
dc.date.accessioned	2024-03-14T05:39:07Z
dc.date.available	2024-03-14T05:39:07Z
dc.date.issued	2023-09-01
dc.identifier.citation	Batteries, 2023, 9, (9)
dc.identifier.issn	2313-0105
dc.identifier.issn	2313-0105
dc.identifier.uri	http://hdl.handle.net/10453/176713
dc.description.abstract	Despite substantial research efforts in developing high-voltage sodium-ion batteries (SIBs) as high-energy-density alternatives to complement lithium-ion-based energy storage technologies, the lifetime of high-voltage SIBs is still associated with many fundamental scientific questions. In particular, the structure phase transition, oxygen loss, and cathode–electrolyte interphase (CEI) decay are intensely discussed in the field. Synchrotron X-ray and neutron scattering characterization techniques offer unique capabilities for investigating the complex structure and dynamics of high-voltage cathode behavior. In this review, to accelerate the development of stable high-voltage SIBs, we provide a comprehensive and thorough overview of the use of synchrotron X-ray and neutron scattering in studying SIB cathode materials with an emphasis on high-voltage layered transition metal oxide cathodes. We then discuss these characterizations in relation to polyanion-type cathodes, Prussian blue analogues, and organic cathode materials. Finally, future directions of these techniques in high-voltage SIB research are proposed, including CEI studies for polyanion-type cathodes and the extension of neutron scattering techniques, as well as the integration of morphology and phase characterizations.
dc.language	English
dc.publisher	MDPI
dc.relation.ispartof	Batteries
dc.relation.isbasedon	10.3390/batteries9090461
dc.rights	info:eu-repo/semantics/openAccess
dc.subject.classification	4008 Electrical engineering
dc.subject.classification	4014 Manufacturing engineering
dc.title	Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review
dc.type	Journal Article
utslib.citation.volume	9
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access	*
dc.date.updated	2024-03-14T05:39:05Z
pubs.issue	9
pubs.publication-status	Published
pubs.volume	9
utslib.citation.issue	9

Abstract:

Despite substantial research efforts in developing high-voltage sodium-ion batteries (SIBs) as high-energy-density alternatives to complement lithium-ion-based energy storage technologies, the lifetime of high-voltage SIBs is still associated with many fundamental scientific questions. In particular, the structure phase transition, oxygen loss, and cathode–electrolyte interphase (CEI) decay are intensely discussed in the field. Synchrotron X-ray and neutron scattering characterization techniques offer unique capabilities for investigating the complex structure and dynamics of high-voltage cathode behavior. In this review, to accelerate the development of stable high-voltage SIBs, we provide a comprehensive and thorough overview of the use of synchrotron X-ray and neutron scattering in studying SIB cathode materials with an emphasis on high-voltage layered transition metal oxide cathodes. We then discuss these characterizations in relation to polyanion-type cathodes, Prussian blue analogues, and organic cathode materials. Finally, future directions of these techniques in high-voltage SIB research are proposed, including CEI studies for polyanion-type cathodes and the extension of neutron scattering techniques, as well as the integration of morphology and phase characterizations.

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http://hdl.handle.net/10453/176713