Gold Microstructures by Thermolysis of Gold(III) Di-isopropyldithiocarbamate Complexes

Angeloski, A; Flower-Donaldson, K; Matar, F; Hayes, DC; Duman, MN; Oldfield, DT; Westerhausen, MT; McDonagh, AM

Gold Microstructures by Thermolysis of Gold(III) Di-isopropyldithiocarbamate Complexes

Angeloski, A

Flower-Donaldson, K Matar, F Hayes, DC Duman, MN Oldfield, DT Westerhausen, MT McDonagh, AM

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Publisher:: WILEY-V C H VERLAG GMBH
Publication Type:: Journal Article
Citation:: ChemNanoMat, 2024, 10, (3)
Issue Date:: 2024-03-01

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Field	Value	Language
dc.contributor.author	Angeloski, A https://orcid.org/0000-0003-4395-1829
dc.contributor.author	Flower-Donaldson, K
dc.contributor.author	Matar, F
dc.contributor.author	Hayes, DC
dc.contributor.author	Duman, MN
dc.contributor.author	Oldfield, DT
dc.contributor.author	Westerhausen, MT
dc.contributor.author	McDonagh, AM
dc.date.accessioned	2024-12-16T03:47:31Z
dc.date.available	2024-12-16T03:47:31Z
dc.date.issued	2024-03-01
dc.identifier.citation	ChemNanoMat, 2024, 10, (3)
dc.identifier.issn	2199-692X
dc.identifier.issn	2199-692X
dc.identifier.uri	http://hdl.handle.net/10453/182565
dc.description.abstract	Elemental gold was formed by thermolysis of gold(III) dithiocarbamate single-source precursors, which exist as two complexes. The complexes were readily synthesised from the reaction between chloroauric acid and sodium di-isopropyldithiocarbamate and could be isolated from each other. The thermal decomposition processes were evaluated using thermogravimetry and electrical resistance measurements. The structure and purity of the resultant gold was examined using scanning electron microscopy. The resultant gold materials were drastically different and dependent on the thermolysed complex.
dc.language	English
dc.publisher	WILEY-V C H VERLAG GMBH
dc.relation.ispartof	ChemNanoMat
dc.relation.isbasedon	10.1002/cnma.202300514
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 1007 Nanotechnology
dc.subject.classification	3403 Macromolecular and materials chemistry
dc.subject.classification	4018 Nanotechnology
dc.title	Gold Microstructures by Thermolysis of Gold(III) Di-isopropyldithiocarbamate Complexes
dc.type	Journal Article
utslib.citation.volume	10
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	1007 Nanotechnology
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/UTS Groups
pubs.organisational-group	University of Technology Sydney/UTS Groups/Centre for Clean Energy Technology (CCET)
utslib.copyright.status	open_access	*
dc.rights.license	This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND 4.0). To view a copy of this license, visit https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.date.updated	2024-12-16T03:47:30Z
pubs.issue	3
pubs.publication-status	Published
pubs.volume	10
utslib.citation.issue	3

Abstract:

Elemental gold was formed by thermolysis of gold(III) dithiocarbamate single-source precursors, which exist as two complexes. The complexes were readily synthesised from the reaction between chloroauric acid and sodium di-isopropyldithiocarbamate and could be isolated from each other. The thermal decomposition processes were evaluated using thermogravimetry and electrical resistance measurements. The structure and purity of the resultant gold was examined using scanning electron microscopy. The resultant gold materials were drastically different and dependent on the thermolysed complex.

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http://hdl.handle.net/10453/182565