Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries.

Zhou, C; Ding, Z; Ying, S; Jiang, H; Wang, Y; Fang, T; Zhang, Y; Sun, B; Tang, X; Liu, X

Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries.

Zhou, C Ding, Z Ying, S Jiang, H Wang, Y Fang, T Zhang, Y Sun, B

Tang, X Liu, X

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Publisher:: SHANGHAI JIAO TONG UNIV PRESS
Publication Type:: Journal Article
Citation:: Nanomicro Lett, 2024, 17, (1), pp. 58
Issue Date:: 2024-11-07

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Field	Value	Language
dc.contributor.author	Zhou, C
dc.contributor.author	Ding, Z
dc.contributor.author	Ying, S
dc.contributor.author	Jiang, H
dc.contributor.author	Wang, Y
dc.contributor.author	Fang, T
dc.contributor.author	Zhang, Y
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Tang, X
dc.contributor.author	Liu, X
dc.date.accessioned	2025-01-02T03:55:06Z
dc.date.available	2024-09-29
dc.date.available	2025-01-02T03:55:06Z
dc.date.issued	2024-11-07
dc.identifier.citation	Nanomicro Lett, 2024, 17, (1), pp. 58
dc.identifier.issn	2311-6706
dc.identifier.issn	2150-5551
dc.identifier.uri	http://hdl.handle.net/10453/182796
dc.description.abstract	Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources, intrinsic safety, and high theoretical capacity. Nevertheless, the uncontrollable zinc dendrite growth and spontaneous shuttle effect of active species have prohibited their practical implementation. Herein, a double-layered protective film based on zinc-ethylenediamine tetramethylene phosphonic acid (ZEA) artificial film and ZnF2-rich solid electrolyte interphase (SEI) layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The ZEA-based artificial film shows strong affinity for the ZnF2-rich SEI layer, therefore effectively suppressing the SEI breakage and facilitating the construction of double-layered protective film on the zinc metal anode. Such double-layered architecture not only modulates Zn2+ flux and suppresses the zinc dendrite growth, but also blocks the direct contact between the metal anode and electrolyte, thus mitigating the corrosion from the active species. When employing optimized metal anodes and electrolytes, the as-developed zinc-(dual) halogen batteries present high areal capacity and satisfactory cycling stability. This work provides a new avenue for developing aqueous zinc-(dual) halogen batteries.
dc.format	Electronic
dc.language	eng
dc.publisher	SHANGHAI JIAO TONG UNIV PRESS
dc.relation.ispartof	Nanomicro Lett
dc.relation.isbasedon	10.1007/s40820-024-01551-w
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject.classification	3403 Macromolecular and materials chemistry
dc.subject.classification	4016 Materials engineering
dc.subject.classification	4018 Nanotechnology
dc.title	Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries.
dc.type	Journal Article
utslib.citation.volume	17
utslib.location.activity	Germany
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/UTS Groups
pubs.organisational-group	University of Technology Sydney/UTS Groups/Centre for Clean Energy Technology (CCET)
utslib.copyright.status	closed_access	*
dc.date.updated	2025-01-02T03:55:02Z
pubs.issue	1
pubs.publication-status	Published online
pubs.volume	17
utslib.citation.issue	1

Abstract:

Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources, intrinsic safety, and high theoretical capacity. Nevertheless, the uncontrollable zinc dendrite growth and spontaneous shuttle effect of active species have prohibited their practical implementation. Herein, a double-layered protective film based on zinc-ethylenediamine tetramethylene phosphonic acid (ZEA) artificial film and ZnF2-rich solid electrolyte interphase (SEI) layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The ZEA-based artificial film shows strong affinity for the ZnF2-rich SEI layer, therefore effectively suppressing the SEI breakage and facilitating the construction of double-layered protective film on the zinc metal anode. Such double-layered architecture not only modulates Zn2+ flux and suppresses the zinc dendrite growth, but also blocks the direct contact between the metal anode and electrolyte, thus mitigating the corrosion from the active species. When employing optimized metal anodes and electrolytes, the as-developed zinc-(dual) halogen batteries present high areal capacity and satisfactory cycling stability. This work provides a new avenue for developing aqueous zinc-(dual) halogen batteries.

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http://hdl.handle.net/10453/182796