Electrochemical coupling in subnanometer pores/channels for rechargeable batteries.

Lei, Y-J; Zhao, L; Lai, W-H; Huang, Z; Sun, B; Jaumaux, P; Sun, K; Wang, Y-X; Wang, G

Electrochemical coupling in subnanometer pores/channels for rechargeable batteries.

Lei, Y-J Zhao, L Lai, W-H Huang, Z Sun, B

Jaumaux, P Sun, K Wang, Y-X Wang, G

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Publisher:: ROYAL SOC CHEMISTRY
Publication Type:: Journal Article
Citation:: Chem Soc Rev, 2024, 53, (8), pp. 3829-3895
Issue Date:: 2024-04-22

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Field	Value	Language
dc.contributor.author	Lei, Y-J
dc.contributor.author	Zhao, L
dc.contributor.author	Lai, W-H
dc.contributor.author	Huang, Z
dc.contributor.author	Sun, B https://orcid.org/0000-0002-4365-486X
dc.contributor.author	Jaumaux, P
dc.contributor.author	Sun, K
dc.contributor.author	Wang, Y-X
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578
dc.date.accessioned	2025-01-03T00:00:20Z
dc.date.available	2025-01-03T00:00:20Z
dc.date.issued	2024-04-22
dc.identifier.citation	Chem Soc Rev, 2024, 53, (8), pp. 3829-3895
dc.identifier.issn	0306-0012
dc.identifier.issn	1460-4744
dc.identifier.uri	http://hdl.handle.net/10453/182871
dc.description.abstract	Subnanometer pores/channels (SNPCs) play crucial roles in regulating electrochemical redox reactions for rechargeable batteries. The delicately designed and tailored porous structure of SNPCs not only provides ample space for ion storage but also facilitates efficient ion diffusion within the electrodes in batteries, which can greatly improve the electrochemical performance. However, due to current technological limitations, it is challenging to synthesize and control the quality, storage, and transport of nanopores at the subnanometer scale, as well as to understand the relationship between SNPCs and performances. In this review, we systematically classify and summarize materials with SNPCs from a structural perspective, dividing them into one-dimensional (1D) SNPCs, two-dimensional (2D) SNPCs, and three-dimensional (3D) SNPCs. We also unveil the unique physicochemical properties of SNPCs and analyse electrochemical couplings in SNPCs for rechargeable batteries, including cathodes, anodes, electrolytes, and functional materials. Finally, we discuss the challenges that SNPCs may face in electrochemical reactions in batteries and propose future research directions.
dc.format	Electronic
dc.language	eng
dc.publisher	ROYAL SOC CHEMISTRY
dc.relation	http://purl.org/au-research/grants/arc/FT180100705
dc.relation	http://purl.org/au-research/grants/arc/IH180100020
dc.relation	http://purl.org/au-research/grants/arc/DP210101389
dc.relation	http://purl.org/au-research/grants/arc/LP200200926
dc.relation.ispartof	Chem Soc Rev
dc.relation.isbasedon	10.1039/d3cs01043k
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.subject.classification	34 Chemical sciences
dc.subject.classification	40 Engineering
dc.title	Electrochemical coupling in subnanometer pores/channels for rechargeable batteries.
dc.type	Journal Article
utslib.citation.volume	53
utslib.location.activity	England
utslib.for	03 Chemical Sciences
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Science
pubs.organisational-group	University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	University of Technology Sydney/UTS Groups
pubs.organisational-group	University of Technology Sydney/UTS Groups/Centre for Clean Energy Technology (CCET)
utslib.copyright.status	closed_access	*
dc.date.updated	2025-01-03T00:00:16Z
pubs.issue	8
pubs.publication-status	Published online
pubs.volume	53
utslib.citation.issue	8

Abstract:

Subnanometer pores/channels (SNPCs) play crucial roles in regulating electrochemical redox reactions for rechargeable batteries. The delicately designed and tailored porous structure of SNPCs not only provides ample space for ion storage but also facilitates efficient ion diffusion within the electrodes in batteries, which can greatly improve the electrochemical performance. However, due to current technological limitations, it is challenging to synthesize and control the quality, storage, and transport of nanopores at the subnanometer scale, as well as to understand the relationship between SNPCs and performances. In this review, we systematically classify and summarize materials with SNPCs from a structural perspective, dividing them into one-dimensional (1D) SNPCs, two-dimensional (2D) SNPCs, and three-dimensional (3D) SNPCs. We also unveil the unique physicochemical properties of SNPCs and analyse electrochemical couplings in SNPCs for rechargeable batteries, including cathodes, anodes, electrolytes, and functional materials. Finally, we discuss the challenges that SNPCs may face in electrochemical reactions in batteries and propose future research directions.

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http://hdl.handle.net/10453/182871