Manganese-based layered coordination polymer: Synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries

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Journal Article
Inorganic Chemistry, 2013, 52 (6), pp. 2817 - 2822
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Manganese-based layered coordination polymer ([Mn(tfbdc)(4,4′-bpy) (H2O)2], Mn-LCP) with microporous structure was synthesized by reaction of 2,3,5,6-tetrafluoroterephthalatic acid(H 2tfbdc) and 4,4′-bipyridine(4,4′-bpy) with manganese(II) acetate tetrahydrate in water solution. Mn-LCP was characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray single-crystal structure analysis, and powder X-ray diffraction. Magnetic susceptibility data from 300 to 1.8K show that there is a weak antiferromagnetic exchange between Mn(II) ions in Mn-LCP. As anode material, the Mn-LCP electrode exhibits an irreversible high capacity in the first discharge process and a reversible lithium storage capacity of up to about 390 mA h/g from the fourth cycle. It might provide a new method for finding new electrode materials in lithium-ion batteries © 2013 American Chemical Society.
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