Deposition of highly porous nanocrystalline platinum on functionalized substrates through fluorine-induced decomposition of Pt(PF<inf>3</inf>) <inf>4</inf> adsorbates

Randolph, SJ; Botman, A; Toth, M

Deposition of highly porous nanocrystalline platinum on functionalized substrates through fluorine-induced decomposition of Pt(PF<inf>3</inf>) <inf>4</inf> adsorbates

Randolph, SJ Botman, A Toth, M

Permalink

Publication Type:: Journal Article
Citation:: Particle and Particle Systems Characterization, 2013, 30 (8), pp. 672 - 677
Issue Date:: 2013-08-01

Open Access

Copyright Clearance Process

Recently Added
In Progress
Open Access

This item is open access.

Adobe PDF

Download full textAdobe PDF (7.23 MB)

View on publisher's site

View statistics

Full metadata record

Field	Value	Language
dc.contributor.author	Randolph, SJ	en_US
dc.contributor.author	Botman, A	en_US
dc.contributor.author	Toth, M https://orcid.org/0000-0003-1564-4899	en_US
dc.date.issued	2013-08-01	en_US
dc.identifier.citation	Particle and Particle Systems Characterization, 2013, 30 (8), pp. 672 - 677	en_US
dc.identifier.issn	0934-0866	en_US
dc.identifier.uri	http://hdl.handle.net/10453/27905
dc.description.abstract	Nanocrystalline platinum is synthesized at room temperature by co-injecting Pt(PF3)4 and XeF2 vapors onto solid supports in vacuum. The Pt nucleation time scales with chemisorbed fluorine coverage, which is controlled by pre-dosing supports with XeF2, and by optional electron or ion beam irradiation under flowing XeF2. The latter is used to increase the chemisorbed fluorine coverage and localize the Pt growth process. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.	en_US
dc.relation.ispartof	Particle and Particle Systems Characterization	en_US
dc.relation.isbasedon	10.1002/ppsc.201300036	en_US
dc.subject.classification	Chemical Engineering	en_US
dc.title	Deposition of highly porous nanocrystalline platinum on functionalized substrates through fluorine-induced decomposition of Pt(PF<inf>3</inf>) <inf>4</inf> adsorbates	en_US
dc.type	Journal Article
utslib.citation.volume	8	en_US
utslib.citation.volume	30	en_US
utslib.for	0904 Chemical Engineering	en_US
utslib.for	0299 Other Physical Sciences	en_US
utslib.for	0913 Mechanical Engineering	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - IBMD - Initiative for Biomedical Devices
pubs.organisational-group	/University of Technology Sydney/Strength - MTEE - Research Centre Materials and Technology for Energy Efficiency
utslib.copyright.status	open_access
pubs.issue	8	en_US
pubs.publication-status	Published	en_US
pubs.volume	30	en_US

Abstract:

Nanocrystalline platinum is synthesized at room temperature by co-injecting Pt(PF3)4 and XeF2 vapors onto solid supports in vacuum. The Pt nucleation time scales with chemisorbed fluorine coverage, which is controlled by pre-dosing supports with XeF2, and by optional electron or ion beam irradiation under flowing XeF2. The latter is used to increase the chemisorbed fluorine coverage and localize the Pt growth process. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/27905