Polymeric di- and discrete trinuclear silver(I) assemblies incorporating γ-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N′-bis(acetylacetone)cyclohexanediimine units

Zhu, BX; Zhang, QL; Zhang, YQ; Tao, Z; Clegg, JK; Reimers, JR; Lindoy, LF; Wei, G

Polymeric di- and discrete trinuclear silver(I) assemblies incorporating γ-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N′-bis(acetylacetone)cyclohexanediimine units

Zhu, BX Zhang, QL Zhang, YQ Tao, Z Clegg, JK Reimers, JR

Lindoy, LF Wei, G

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Publication Type:: Journal Article
Citation:: Journal of the Chemical Society. Dalton Transactions, 2009, (25), pp. 4896 - 4900
Issue Date:: 2009-06-16

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Field	Value	Language
dc.contributor.author	Zhu, BX	en_US
dc.contributor.author	Zhang, QL	en_US
dc.contributor.author	Zhang, YQ	en_US
dc.contributor.author	Tao, Z	en_US
dc.contributor.author	Clegg, JK	en_US
dc.contributor.author	Reimers, JR https://orcid.org/0000-0001-5157-7422	en_US
dc.contributor.author	Lindoy, LF	en_US
dc.contributor.author	Wei, G	en_US
dc.date.issued	2009-06-16	en_US
dc.identifier.citation	Journal of the Chemical Society. Dalton Transactions, 2009, (25), pp. 4896 - 4900	en_US
dc.identifier.issn	1477-9226	en_US
dc.identifier.uri	http://hdl.handle.net/10453/28172
dc.description.abstract	Diastereopure (1R,2R)-N,N′-bis(acetylacetone)cyclohexanedi-imine L 1 and its corresponding (1R,2R)L 1/(1S,2S)L 2 enantiomeric mixture react with AgNO3 to yield the unusual coordination polymer [Ag2(L 1)(L 2)(NO3)2]n (1) and the unique trimetallic discrete species ([Ag3(L 1)3(μ3-O,O,O-NO3)(H2O)3]2(NO3))(NO3)3·8.5H2O (2) which incorporates a symmetrical μ3-bridging nitrato group that gives rise to a C3-symmetric triskelion motif; both species also feature γ-carbon η1 aryl-like coordination of neutral bridging acetylacetone-imine units to the respective Ag(I) centres. © 2009 The Royal Society of Chemistry.	en_US
dc.relation.ispartof	Journal of the Chemical Society. Dalton Transactions	en_US
dc.relation.isbasedon	10.1039/b903467f	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Polymeric di- and discrete trinuclear silver(I) assemblies incorporating γ-carbon bonded, neutral acetylacetone-imine motifs assembled from racemic and diastereopure N,N′-bis(acetylacetone)cyclohexanediimine units	en_US
dc.type	Journal Article
utslib.citation.volume	25	en_US
utslib.for	0399 Other Chemical Sciences	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0307 Theoretical and Computational Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	closed_access
pubs.issue	25	en_US
pubs.publication-status	Published	en_US

Abstract:

Diastereopure (1R,2R)-N,N′-bis(acetylacetone)cyclohexanedi-imine L 1 and its corresponding (1R,2R)L 1/(1S,2S)L 2 enantiomeric mixture react with AgNO3 to yield the unusual coordination polymer [Ag2(L 1)(L 2)(NO3)2]n (1) and the unique trimetallic discrete species ([Ag3(L 1)3(μ3-O,O,O-NO3)(H2O)3]2(NO3))(NO3)3·8.5H2O (2) which incorporates a symmetrical μ3-bridging nitrato group that gives rise to a C3-symmetric triskelion motif; both species also feature γ-carbon η1 aryl-like coordination of neutral bridging acetylacetone-imine units to the respective Ag(I) centres. © 2009 The Royal Society of Chemistry.

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http://hdl.handle.net/10453/28172