A new class of self-assembled monolayers on gold using an alkynyl group as a linker

Ford, MJ; Hoft, RC; Gale, JD; McDonagh, AM

A new class of self-assembled monolayers on gold using an alkynyl group as a linker

Ford, MJ

Hoft, RC Gale, JD McDonagh, AM

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Publication Type:: Conference Proceeding
Citation:: Proceedings of the 2006 International Conference on Nanoscience and Nanotechnology, ICONN, 2006, pp. 645 - 648
Issue Date:: 2006-12-01

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Field	Value	Language
dc.contributor.author	Ford, MJ https://orcid.org/0000-0002-8595-5900	en_US
dc.contributor.author	Hoft, RC	en_US
dc.contributor.author	Gale, JD	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.date.issued	2006-12-01	en_US
dc.identifier.citation	Proceedings of the 2006 International Conference on Nanoscience and Nanotechnology, ICONN, 2006, pp. 645 - 648	en_US
dc.identifier.isbn	1424404533	en_US
dc.identifier.isbn	9781424404537	en_US
dc.identifier.uri	http://hdl.handle.net/10453/2936
dc.description.abstract	The geometry and energetics for adsorption of ethynylbenzene on Au(111) have been studied using Density Functional Theory. The alkynyl group, following removal of the terminal H atom, adsorbs covalently to the surface in the fcc hollow site with a bond energy of about 70 kcal.mol-1. Intermediate adsorption states are also possible via a hydrogen 1,2 shift to form a surface-bound vinylidene, or through the opening of the C-C triple bond without removing the hydrogen atom. © 2006 IEEE.	en_US
dc.relation.ispartof	Proceedings of the 2006 International Conference on Nanoscience and Nanotechnology, ICONN	en_US
dc.relation.isbasedon	10.1109/ICONN.2006.340700	en_US
dc.title	A new class of self-assembled monolayers on gold using an alkynyl group as a linker	en_US
dc.type	Conference Proceeding
utslib.for	1007 Nanotechnology	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0302 Inorganic Chemistry	en_US
dc.location.activity	Brisbane QLD, Australia	en_US
dc.location.activity	Bangkok, Thailand
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/DVC (Research)
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access
pubs.publication-status	Published	en_US

Abstract:

The geometry and energetics for adsorption of ethynylbenzene on Au(111) have been studied using Density Functional Theory. The alkynyl group, following removal of the terminal H atom, adsorbs covalently to the surface in the fcc hollow site with a bond energy of about 70 kcal.mol-1. Intermediate adsorption states are also possible via a hydrogen 1,2 shift to form a surface-bound vinylidene, or through the opening of the C-C triple bond without removing the hydrogen atom. © 2006 IEEE.

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http://hdl.handle.net/10453/2936