Bis(κ<sup>2</sup>S,S′-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C-H⋯Ni interactions and physical properties
- Publication Type:
- Journal Article
- Journal of Molecular Structure, 2016, 1113 pp. 127 - 132
- Issue Date:
© 2016 Elsevier B.V. All rights reserved. The molecular structure of bis(κ2S,S′-di(isopropyl)dithiocarbamato)nickel(II) has been examined by single crystal X-ray diffraction. The data reveal a C-H·Ni anagostic interaction arising from the interaction of two non-equivalent molecules within the crystal. Thermal analysis data show that the complex decomposes at ∼330 °C. The structure of the resultant NiS material was examined using scanning electron microscopy and energy dispersive X-ray spectroscopy which revealed NiS nanowires.
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