Organometallic complexes for nonlinear optics: Part 25. Quadratic and cubic hyperpolarizabilities of some dipolar and quadrupolar gold and ruthenium complexes

Hurst, SK; Cifuentes, MP; McDonagh, AM; Humphrey, MG; Samoc, M; Luther-Davies, B; Asselberghs, I; Persoons, A

Organometallic complexes for nonlinear optics: Part 25. Quadratic and cubic hyperpolarizabilities of some dipolar and quadrupolar gold and ruthenium complexes

Hurst, SK Cifuentes, MP McDonagh, AM

Humphrey, MG Samoc, M Luther-Davies, B Asselberghs, I Persoons, A

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Publisher:: Elsevier
Publication Type:: Journal Article
Citation:: Journal of Organometallic Chemistry, 2002, 642 (NA), pp. 259 - 267
Issue Date:: 2002-01

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Field	Value	Language
dc.contributor.author	Hurst, SK	en_US
dc.contributor.author	Cifuentes, MP	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.contributor.author	Humphrey, MG	en_US
dc.contributor.author	Samoc, M	en_US
dc.contributor.author	Luther-Davies, B	en_US
dc.contributor.author	Asselberghs, I	en_US
dc.contributor.author	Persoons, A	en_US
dc.date.issued	2002-01	en_US
dc.identifier.citation	Journal of Organometallic Chemistry, 2002, 642 (NA), pp. 259 - 267	en_US
dc.identifier.issn	0022-328X	en_US
dc.identifier.uri	http://hdl.handle.net/10453/518
dc.description.abstract	A range of dipolar and quadrupolar gold and ruthenium acetylides have been prepared and their electrochemical (Ru complexes) and nonlinear optical properties assessed; electronic communication between the metal centers diminishes as the ?-delocalizable bridge is lengthened and quadratic NLO merit increases on replacing triarylphosphine by trialkylphosphine. One diruthenium example has the largest two-photon absorption cross-section/molecular weight value observed thus far for an organometallic complex.	en_US
dc.publisher	Elsevier	en_US
dc.relation.ispartof	Journal of Organometallic Chemistry	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.title	Organometallic complexes for nonlinear optics: Part 25. Quadratic and cubic hyperpolarizabilities of some dipolar and quadrupolar gold and ruthenium complexes	en_US
dc.type	Journal Article
utslib.citation.volume	NA	en_US
utslib.citation.volume	642	en_US
utslib.for	1007 Nanotechnology	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0305 Organic Chemistry	en_US
utslib.for	0399 Other Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.consider-herdc	false	en_US
pubs.issue	NA	en_US
pubs.volume	642	en_US

Abstract:

A range of dipolar and quadrupolar gold and ruthenium acetylides have been prepared and their electrochemical (Ru complexes) and nonlinear optical properties assessed; electronic communication between the metal centers diminishes as the ?-delocalizable bridge is lengthened and quadratic NLO merit increases on replacing triarylphosphine by trialkylphosphine. One diruthenium example has the largest two-photon absorption cross-section/molecular weight value observed thus far for an organometallic complex.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/518