Titanium dioxide nanoparticles functionalized with Pd and W complexes of a catecholphosphane ligand

Lucas, NT; Hook, JM; McDonagh, AM; Colbran, SB

Titanium dioxide nanoparticles functionalized with Pd and W complexes of a catecholphosphane ligand

Lucas, NT Hook, JM McDonagh, AM

Colbran, SB

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Publication Type:: Journal Article
Citation:: European Journal of Inorganic Chemistry, 2005, (3), pp. 496 - 503
Issue Date:: 2005-02-04

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Field	Value	Language
dc.contributor.author	Lucas, NT	en_US
dc.contributor.author	Hook, JM	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.contributor.author	Colbran, SB	en_US
dc.date.issued	2005-02-04	en_US
dc.identifier.citation	European Journal of Inorganic Chemistry, 2005, (3), pp. 496 - 503	en_US
dc.identifier.issn	1434-1948	en_US
dc.identifier.uri	http://hdl.handle.net/10453/577
dc.description.abstract	Palladium and tungsten complexes containing the bifunctional ligand 4-diphenylphosphanylcatechol (L1) have been synthesized. The catecholate functionality strongly binds to titanium dioxide nanoparticles, effectively anchoring the complexes to the TiO2 surface. Solid-state 31P NMR spectroscopy was used to probe the surface-bound compounds. Diffuse reflectance infrared spectroscopy also provided data on surface-bound tungsten carbonyl complexes. Preliminary experiments show that the palladium phosphane complex [PdBr2(L1)2] supported on TiO2 catalyzes the Sonogashira coupling of phenylacetylene with 4-iodonitrobenzene. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).	en_US
dc.relation.ispartof	European Journal of Inorganic Chemistry	en_US
dc.relation.isbasedon	10.1002/ejic.200400584	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Titanium dioxide nanoparticles functionalized with Pd and W complexes of a catecholphosphane ligand	en_US
dc.type	Journal Article
utslib.citation.volume	3	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0399 Other Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	3	en_US
pubs.publication-status	Published	en_US

Abstract:

Palladium and tungsten complexes containing the bifunctional ligand 4-diphenylphosphanylcatechol (L1) have been synthesized. The catecholate functionality strongly binds to titanium dioxide nanoparticles, effectively anchoring the complexes to the TiO2 surface. Solid-state 31P NMR spectroscopy was used to probe the surface-bound compounds. Diffuse reflectance infrared spectroscopy also provided data on surface-bound tungsten carbonyl complexes. Preliminary experiments show that the palladium phosphane complex [PdBr2(L1)2] supported on TiO2 catalyzes the Sonogashira coupling of phenylacetylene with 4-iodonitrobenzene. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

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http://hdl.handle.net/10453/577