Covalently linked ferrocenyl quinones: Proton-dependent redox behavior and charge redistribution

Colbran, SB; Lee, ST; Lonnon, DG; Maharaj, FJD; McDonagh, AM; Walker, KA; Young, RD

Covalently linked ferrocenyl quinones: Proton-dependent redox behavior and charge redistribution

Colbran, SB Lee, ST Lonnon, DG Maharaj, FJD McDonagh, AM

Walker, KA Young, RD

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Publication Type:: Journal Article
Citation:: Organometallics, 2006, 25 (9), pp. 2216 - 2224
Issue Date:: 2006-04-24

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Field	Value	Language
dc.contributor.author	Colbran, SB	en_US
dc.contributor.author	Lee, ST	en_US
dc.contributor.author	Lonnon, DG	en_US
dc.contributor.author	Maharaj, FJD	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.contributor.author	Walker, KA	en_US
dc.contributor.author	Young, RD	en_US
dc.date.issued	2006-04-24	en_US
dc.identifier.citation	Organometallics, 2006, 25 (9), pp. 2216 - 2224	en_US
dc.identifier.issn	0276-7333	en_US
dc.identifier.uri	http://hdl.handle.net/10453/608
dc.description.abstract	The proton-dependent redox chemistry of dyads comprised of a ferrocenyl electron donor directly linked to a hydroquinonyl electron donor or to a quinone electron acceptor by a single covalent bond has been characterized. Ferrocenyl-1,4-hydroquinone (2), ferrocenyl-1,4-benzoquinone (3), 3-ferrocenyl-l,2catechol (5), and the precursors ferrocenyl-1,4-dimethoxybenzene (1) and 3-ferrocenyl-l,2-dimethoxybenzene (4) were studied; also the unstable compound 3-ferrocenyl-l,2-benzoquinone (6) was observed in the spectroelectrochemistry of 5. Detailed cyclic voltammetry, coulommetry, and UV-vis-NIR spectroelectrochemistry experiments allied with EPR, NMR, and Mössbauer spectroscopy were used to probe the pH-dependent redox chemistry and electron distribution within the compounds. © 2006 American Chemical Society.	en_US
dc.relation.ispartof	Organometallics	en_US
dc.relation.isbasedon	10.1021/om060040x	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.title	Covalently linked ferrocenyl quinones: Proton-dependent redox behavior and charge redistribution	en_US
dc.type	Journal Article
utslib.citation.volume	9	en_US
utslib.citation.volume	25	en_US
utslib.for	0399 Other Chemical Sciences	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0305 Organic Chemistry	en_US
dc.location.activity	ISI000236973500016	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	9	en_US
pubs.publication-status	Published	en_US
pubs.volume	25	en_US

Abstract:

The proton-dependent redox chemistry of dyads comprised of a ferrocenyl electron donor directly linked to a hydroquinonyl electron donor or to a quinone electron acceptor by a single covalent bond has been characterized. Ferrocenyl-1,4-hydroquinone (2), ferrocenyl-1,4-benzoquinone (3), 3-ferrocenyl-l,2catechol (5), and the precursors ferrocenyl-1,4-dimethoxybenzene (1) and 3-ferrocenyl-l,2-dimethoxybenzene (4) were studied; also the unstable compound 3-ferrocenyl-l,2-benzoquinone (6) was observed in the spectroelectrochemistry of 5. Detailed cyclic voltammetry, coulommetry, and UV-vis-NIR spectroelectrochemistry experiments allied with EPR, NMR, and Mössbauer spectroscopy were used to probe the pH-dependent redox chemistry and electron distribution within the compounds. © 2006 American Chemical Society.

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http://hdl.handle.net/10453/608