Controlled Assembly of Conducting Monomers for Molecular Electronics

Zareie, HM; Ma, H; Reed, BW; Jen, AK; Sarikaya, M

Controlled Assembly of Conducting Monomers for Molecular Electronics

Zareie, HM Ma, H Reed, BW Jen, AK Sarikaya, M

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Publisher:: American Chemical Society
Publication Type:: Journal Article
Citation:: Nano Letters, 2003, 3 (2), pp. 139 - 142
Issue Date:: 2003-01

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Field	Value	Language
dc.contributor.author	Zareie, HM	en_US
dc.contributor.author	Ma, H	en_US
dc.contributor.author	Reed, BW	en_US
dc.contributor.author	Jen, AK	en_US
dc.contributor.author	Sarikaya, M	en_US
dc.date.issued	2003-01	en_US
dc.identifier.citation	Nano Letters, 2003, 3 (2), pp. 139 - 142	en_US
dc.identifier.issn	1530-6984	en_US
dc.identifier.uri	http://hdl.handle.net/10453/8435
dc.description.abstract	We report controlled self-assemblies of two molecules as crystalline arrays on gold substrates at room temperature. The size, shape, orientation, and ordered assemblies of molecular wires can be engineered through a delicate interplay of the intermolecular - stacking and chemisorptive substrate-linker interactions. In particular, the molecule based on a fused aromatic, anthracene, forms an ordered 2D stacked array. Through scanning tunneling spectroscopy, we demonstrate changes in the electronic behavior of single molecules that form into superlattices. The ability to assemble predictable 2D crystals and understand the order-related electronic behavior of single molecular components could allow for the future design of nanopatterned arrays as a controlled platform toward further miniaturization of electronic devices.	en_US
dc.publisher	American Chemical Society	en_US
dc.relation.ispartof	Nano Letters	en_US
dc.relation.isbasedon	http://dx.doi.org/10.1021/nl025833x	en_US
dc.subject.classification	Nanoscience & Nanotechnology	en_US
dc.title	Controlled Assembly of Conducting Monomers for Molecular Electronics	en_US
dc.type	Journal Article
utslib.citation.volume	2	en_US
utslib.citation.volume	3	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	closed_access
pubs.consider-herdc	false	en_US
pubs.issue	2	en_US
pubs.volume	3	en_US

Abstract:

We report controlled self-assemblies of two molecules as crystalline arrays on gold substrates at room temperature. The size, shape, orientation, and ordered assemblies of molecular wires can be engineered through a delicate interplay of the intermolecular - stacking and chemisorptive substrate-linker interactions. In particular, the molecule based on a fused aromatic, anthracene, forms an ordered 2D stacked array. Through scanning tunneling spectroscopy, we demonstrate changes in the electronic behavior of single molecules that form into superlattices. The ability to assemble predictable 2D crystals and understand the order-related electronic behavior of single molecular components could allow for the future design of nanopatterned arrays as a controlled platform toward further miniaturization of electronic devices.

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http://hdl.handle.net/10453/8435