Interpenetrating inclusion lattices: Comparison of the β-hydroquinone and ellipsoidal clathrate structures

Bishop, R; Craig, DC; Dance, IG; Scudder, ML; Ung, AT

Interpenetrating inclusion lattices: Comparison of the β-hydroquinone and ellipsoidal clathrate structures

Bishop, R Craig, DC Dance, IG Scudder, ML Ung, AT

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Publication Type:: Journal Article
Citation:: Journal of Structural Chemistry, 1999, 40 (5), pp. 663 - 671
Issue Date:: 1999-01-01

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Field	Value	Language
dc.contributor.author	Bishop, R	en_US
dc.contributor.author	Craig, DC	en_US
dc.contributor.author	Dance, IG	en_US
dc.contributor.author	Scudder, ML	en_US
dc.contributor.author	Ung, AT https://orcid.org/0000-0002-5665-0702	en_US
dc.date.issued	1999-01-01	en_US
dc.identifier.citation	Journal of Structural Chemistry, 1999, 40 (5), pp. 663 - 671	en_US
dc.identifier.issn	0022-4766	en_US
dc.identifier.uri	http://hdl.handle.net/10453/8443
dc.description.abstract	Crystallization of 2,7-dimethyltricyclo[4.3.1.13,8]undecane-syn-2,syn-7-diol 2 from acetonitrile or dichloromethane yields the compounds (2)4· (guest) in space group I41/acd which are further examples of the ellipsoidal clathrate structure. Both enantiomers of 2 are linked through (O-H)4 cycles of hydrogen bonds to form a three-dimensional sublattice. Two inversion related sublattices interpenetrate thereby generating a superlattice with guest-occupied voids situated between the two individual sublattices. The two X-ray structures are compared and contrasted with that of Powell's (hydroquinone)3· (SO2) clathrate compound.	en_US
dc.relation.ispartof	Journal of Structural Chemistry	en_US
dc.relation.isbasedon	10.1007/BF02903443	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Interpenetrating inclusion lattices: Comparison of the β-hydroquinone and ellipsoidal clathrate structures	en_US
dc.type	Journal Article
utslib.citation.volume	5	en_US
utslib.citation.volume	40	en_US
utslib.for	030606 Structural Chemistry and Spectroscopy	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0307 Theoretical and Computational Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	5	en_US
pubs.publication-status	Published	en_US
pubs.volume	40	en_US

Abstract:

Crystallization of 2,7-dimethyltricyclo[4.3.1.13,8]undecane-syn-2,syn-7-diol 2 from acetonitrile or dichloromethane yields the compounds (2)4· (guest) in space group I41/acd which are further examples of the ellipsoidal clathrate structure. Both enantiomers of 2 are linked through (O-H)4 cycles of hydrogen bonds to form a three-dimensional sublattice. Two inversion related sublattices interpenetrate thereby generating a superlattice with guest-occupied voids situated between the two individual sublattices. The two X-ray structures are compared and contrasted with that of Powell's (hydroquinone)3· (SO2) clathrate compound.

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http://hdl.handle.net/10453/8443