Multicolor barcoding in a single upconversion crystal
- Publication Type:
- Journal Article
- Journal of the American Chemical Society, 2014, 136 (13), pp. 4893 - 4896
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We report the synthesis of luminescent crystals based on hexagonal-phase NaYF
4 upconversion microrods. The synthetic procedure involves an epitaxial end-on growth of upconversion nanocrystals comprising different lanthanide activators onto the NaYF 4 microrods. This bottom-up method readily affords multicolor-banded crystals in gram quantity by varying the composition of the activators. Importantly, the end-on growth method using one-dimensional microrods as the template enables facile multicolor tuning in a single crystal, which is inaccessible in conventional upconversion nanoparticles. We demonstrate that these novel materials offer opportunities as optical barcodes for anticounterfeiting and multiplexed labeling applications. © 2014 American Chemical Society.
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