Hierarchical Porous Molybdenum Carbide Based Nanomaterials for Electrocatalytic Hydrogen Production.

Liu, Y; Huo, J; Guo, J; Lu, L; Shen, Z; Chen, W; Liu, C; Liu, H

Hierarchical Porous Molybdenum Carbide Based Nanomaterials for Electrocatalytic Hydrogen Production.

Liu, Y Huo, J Guo, J Lu, L Shen, Z Chen, W Liu, C Liu, H

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Publisher:: FRONTIERS MEDIA SA
Publication Type:: Journal Article
Citation:: Frontiers in chemistry, 2020, 8
Issue Date:: 2020-01

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Field	Value	Language
dc.contributor.author	Liu, Y
dc.contributor.author	Huo, J
dc.contributor.author	Guo, J
dc.contributor.author	Lu, L
dc.contributor.author	Shen, Z
dc.contributor.author	Chen, W
dc.contributor.author	Liu, C
dc.contributor.author	Liu, H https://orcid.org/0000-0003-0266-9472
dc.date.accessioned	2020-12-15T00:59:08Z
dc.date.available	2020-04-23
dc.date.available	2020-12-15T00:59:08Z
dc.date.issued	2020-01
dc.identifier.citation	Frontiers in chemistry, 2020, 8
dc.identifier.issn	2296-2646
dc.identifier.issn	2296-2646
dc.identifier.uri	http://hdl.handle.net/10453/144694
dc.description.abstract	The electrocatalytic hydrogen evolution reaction (HER) for the preparation of hydrogen fuel is a very promising technology to solve the shortage of hydrogen storage. However, in practical applications, HER catalysts with excellent performance and moderate price are very rare. Molybdenum carbide (MoxC) has attracted extensive attention due to its electronic structure and natural abundance. Here, a comprehensive review of the preparation and performance control of hierarchical porous molybdenum carbide (HP-MoxC) based catalysts is summarized. The methods for preparing hierarchical porous materials and the regulation of their HER performance are mainly described. Briefly, the HP-MoxC based catalysts were prepared by template method, morphology-conserved transformations method, and secondary conversion method of an organic-inorganic hybrid material. The intrinsic HER kinetics are enhanced by the introduction of a carbon-based support, heteroatom doping, and the construction of a heterostructure. Finally, the future development of HP-MoxC based catalysts is prospected in this review.
dc.format	Electronic-eCollection
dc.language	eng
dc.publisher	FRONTIERS MEDIA SA
dc.relation.ispartof	Frontiers in chemistry
dc.relation.isbasedon	10.3389/fchem.2020.00426
dc.rights	info:eu-repo/semantics/openAccess
dc.title	Hierarchical Porous Molybdenum Carbide Based Nanomaterials for Electrocatalytic Hydrogen Production.
dc.type	Journal Article
utslib.citation.volume	8
utslib.location.activity	Switzerland
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney
utslib.copyright.status	open_access	*
pubs.consider-herdc	false
dc.date.updated	2020-12-15T00:59:04Z
pubs.publication-status	Published
pubs.volume	8

Abstract:

The electrocatalytic hydrogen evolution reaction (HER) for the preparation of hydrogen fuel is a very promising technology to solve the shortage of hydrogen storage. However, in practical applications, HER catalysts with excellent performance and moderate price are very rare. Molybdenum carbide (MoxC) has attracted extensive attention due to its electronic structure and natural abundance. Here, a comprehensive review of the preparation and performance control of hierarchical porous molybdenum carbide (HP-MoxC) based catalysts is summarized. The methods for preparing hierarchical porous materials and the regulation of their HER performance are mainly described. Briefly, the HP-MoxC based catalysts were prepared by template method, morphology-conserved transformations method, and secondary conversion method of an organic-inorganic hybrid material. The intrinsic HER kinetics are enhanced by the introduction of a carbon-based support, heteroatom doping, and the construction of a heterostructure. Finally, the future development of HP-MoxC based catalysts is prospected in this review.

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http://hdl.handle.net/10453/144694