Optical and redox properties of ruthenium phthalocyanine complexes tuned with axial ligand substituents

Rawling, T; Xiao, H; Lee, ST; Colbran, SB; McDonagh, AM

Optical and redox properties of ruthenium phthalocyanine complexes tuned with axial ligand substituents

Rawling, T

Xiao, H Lee, ST Colbran, SB McDonagh, AM

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Publication Type:: Journal Article
Citation:: Inorganic Chemistry, 2007, 46 (7), pp. 2805 - 2813
Issue Date:: 2007-04-02

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Field	Value	Language
dc.contributor.author	Rawling, T https://orcid.org/0000-0002-6624-6586	en_US
dc.contributor.author	Xiao, H	en_US
dc.contributor.author	Lee, ST	en_US
dc.contributor.author	Colbran, SB	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.date.issued	2007-04-02	en_US
dc.identifier.citation	Inorganic Chemistry, 2007, 46 (7), pp. 2805 - 2813	en_US
dc.identifier.issn	0020-1669	en_US
dc.identifier.uri	http://hdl.handle.net/10453/3567
dc.description.abstract	The optical and electrochemical properties of the ruthenium phthalocyanine complexes [{(t-Bu)4Pc}Ru(4-Rpy)2], where R = NO 2, Me, NH2, and NMe2, are reported. The electron density at the macrocycle may be adjusted using the axial ligand substituents, which have varying electron-donating/withdrawing strengths. Electrochemical data show that the axial pyridine ligand substituents exert significant influence over the phthalocyanine ring-based redox processes. The axial ligands also influence the electronic absorption properties of the complexes with influence also being observed in the electrogenerated oxidized and reduced species. © 2007 American Chemical Society.	en_US
dc.relation.ispartof	Inorganic Chemistry	en_US
dc.relation.isbasedon	10.1021/ic061866u	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Optical and redox properties of ruthenium phthalocyanine complexes tuned with axial ligand substituents	en_US
dc.type	Journal Article
utslib.citation.volume	7	en_US
utslib.citation.volume	46	en_US
utslib.for	0904 Chemical Engineering	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0399 Other Chemical Sciences	en_US
dc.location.activity	ISI000245135900060	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	7	en_US
pubs.publication-status	Published	en_US
pubs.volume	46	en_US

Abstract:

The optical and electrochemical properties of the ruthenium phthalocyanine complexes [{(t-Bu)4Pc}Ru(4-Rpy)2], where R = NO 2, Me, NH2, and NMe2, are reported. The electron density at the macrocycle may be adjusted using the axial ligand substituents, which have varying electron-donating/withdrawing strengths. Electrochemical data show that the axial pyridine ligand substituents exert significant influence over the phthalocyanine ring-based redox processes. The axial ligands also influence the electronic absorption properties of the complexes with influence also being observed in the electrogenerated oxidized and reduced species. © 2007 American Chemical Society.

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